Artificial photosynthesis has the potential to be one of the most promising sciences and technologies for solving the global environmental problems that may threaten the sustainability of humanity, caused by the exhaustion of fossil energy and carbon resources along with the rapid increase of atmospheric carbon dioxide concentration. A further escalation of the “CO2 crisis” now seems inevitable.
Modern research on artificial photosynthesis started in the late 20th century with three major milestones:
light induced water splitting using titanium dioxide (Honda-Fujishima effect: 1972)
water oxidation catalysis (Meyer: 1983)
photocatalytic reduction of CO2 (Lehn: 1986)
Since the previous successful Faraday Discussions meeting on Artificial Photosynthesis in 2011, the cutting edge of artificial photosynthesis research has developed very rapidly with many recent breakthroughs in various challenging approaches. Now the field is coming to a new stage where a definite contribution of the fundamental science and technology of artificial photosynthesis to their practical application is becoming a realistic need from the viewpoint of a globally sustainable society. Within decades artificial photosynthesis can be expected to provide one of the most likely and realistic options to address the needs of society as a whole. It will be important for scientists from many disciplines to work together towards the breakthroughs and developments that will be needed to realise this vision.
Biological approaches to artificial photosynthesis, fundamental processes and theoretical approaches
Key points for discussion will include learning, understanding, and modifying nature to approach artificial photosynthesis:
How does nature exert efficient water oxidation?
What is the structure of the reaction centre?
How does nature protect the reaction centre?
How can we couple light harvesting with electron transfer, proton-coupled electron transfer?
How can we utilize theoretical analysis and prediction for designing systems?
Molecular catalysts for artificial photosynthesis
Crucial points for discussion are water oxidation, hydrogen evolution, and CO2 reduction catalysis:
What are the bottleneck subjects and how can we get through them?
How can we get electrons from water for CO2 reduction?
Inorganic assembly catalysts for artificial photosynthesis
Key points for discussion are visible light responsive semiconductors, polyoxometalates, organic/inorganic hybrid compounds:
How can we improve charge separation?
How can we reduce the effect of defect?
How do hot electrons behave in the conduction band and how can we control the flow of the electrons?
Integration of systems for demonstrating realistic devices
Important points for discussion are systemization, coupling with solar cells, thermal decomposition of water by sunlight, energy payback time, cost payback time, science communication among general society:
How can we design, assemble, and integrate systems?
What is the time schedule?
When will industry join?
How and when does the general public choose to adopt technologies?
02月28日
2017
03月02日
2017
初稿截稿日期
注册截止日期
留言