Two abundant bioaccumulated halogenaged compounds are natural products
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报告开始:2025年01月14日 15:35(Asia/Shanghai)

报告时间:15min

所在会场:[S69] Session 69-Emerging Contaminants in the Marine Environment and Polar Region: Processes, Effects, and Health [S69-3] Emerging Contaminants in the Marine Environment and Polar Region: Processes, Effects, and Health

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摘要
Most pollutants are either directly or indirectly derived from fossil fuels that are free of radiocarbon. Radiocarbon, especially at compound level, is a powerful tool to characterize the source and transport of the pollutants in marine environment. This technique is applied to apportion the source (fossil or biomass) of polyaromatic hydrocarbon in costal sediments, water and aerosols.  
Methoxylated polybrominated diphenyl ethers (MeO-PBDEs) have been found bioaccumulated in the tissues of a variety of aquatic animals and at concentrations comparable to those of anthropogenic halogenated organic compounds, including polychlorinated biphenyls (PCBs). The origin of the MeO-PBDEs has been uncertain; circumstantial evidence supports a natural and/or an industrial source. By analyzing the natural abundance radiocarbon content of two MeO-PBDEs isolated from a True’s beaked whale (Mesoplodon mirus), we show with radiocarbon data that these compounds were naturally produced.
Most pollutants are either directly or indirectly derived from fossil fuels that are free of radiocarbon. Radiocarbon, especially at compound level, is a powerful tool to characterize the source and transport of the pollutants in marine environment. This technique is applied to apportion the source (fossil or biomass) of polyaromatic hydrocarbon in costal sediments, water and aerosols.  
Methoxylated polybrominated diphenyl ethers (MeO-PBDEs) have been found bioaccumulated in the tissues of a variety of aquatic animals and at concentrations comparable to those of anthropogenic halogenated organic compounds, including polychlorinated biphenyls (PCBs). The origin of the MeO-PBDEs has been uncertain; circumstantial evidence supports a natural and/or an industrial source. By analyzing the natural abundance radiocarbon content of two MeO-PBDEs isolated from a True’s beaked whale (Mesoplodon mirus), we show with radiocarbon data that these compounds were naturally produced.
 
关键词
Radiocarbon, compound specifid radiocarbon analysis,,Methoxylated polybrominated diphenyl ethers
报告人
Li Xu
PhD Woods Hole Oceanographic Institution

稿件作者
Li Xu Woods Hole Oceanographic Institution
Chrostopher Reddy Woods Hole Oceanographic Institution
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重要日期
  • 会议日期

    01月13日

    2025

    01月17日

    2025

  • 09月27日 2024

    初稿截稿日期

  • 01月17日 2025

    注册截止日期

主办单位
State Key Laboratory of Marine Environmental Science, Xiamen University
承办单位
State Key Laboratory of Marine Environmental Science, Xiamen University
Department of Earth Sciences, National Natural Science Foundation of China
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